Methods to Estimate Source Zone Depletion of Fuel Releases by Groundwater Flow

We compare two methods for estimating the natural source zone depletion (NSZD) rate at fuel release sites that occurs by groundwater flow through the source zone due to dissolution and transport of biodegradation products. Dissolution is addressed identically in both methods. The “mass budget method”, previously proposed and applied by others, estimates the petroleum hydrocarbon biodegradation rate based on dissolved electron acceptor delivery and dissolved biodegradation product removal by groundwater flow. The mass budget method relies on assumed stoichiometry for the degradation reactions and differences in concentrations of dissolved species (oxygen, nitrate, sulfate, reduced iron, reduced manganese, nonvolatile dissolved organic carbon, methane) at monitoring locations upgradient and downgradient of the source zone. We illustrate a refinement to account for degradation reactions associated with loss of reduced iron from solution. The “carbon budget method,” a simplification of approaches applied by others, addresses carbon‐containing species in solution or lost from solution (precipitated) and does not require assumptions about stoichiometry or information about electron acceptors. We apply both methods to a fuel release site with unusually detailed monitoring data and discuss applicability to more typical and less thoroughly monitored sites. The methods, as would typically be applied, yield similar results but have different constraints and uncertainties. Overall, we conclude that the carbon budget method has greater practical utility as it is simpler, requires fewer assumptions, accounts for most iron‐reducing reactions, and does not include CO₂ that escapes from the saturated to the unsaturated zone.     

Storage and Preservation of Artificial Sweeteners in Groundwater Samples

Compound‐specific standardized sampling and storage methods are not available for artificial sweeteners found in groundwater. This study aimed to understand: (1) the appropriate length of storage time for samples containing acesulfame (ACE), sucralose (SUC), saccharin (SAC), and cyclamate (CYC) in simulated groundwater (SGW); (2) conditions of their stability; and (3) which sampling materials are appropriate for sample collection. The evaluated storage conditions included acidification, headspace, exposure to light, and refrigeration; the evaluated sampling materials included steel, stainless steel, aluminum, polyvinyl chloride, polyamide (nylon), polypropylene (PharMed BPT?) tubing, styrene‐ethylene‐butylene co‐polymer (MasterFlex?) tubing, and polytetrafluoroethylene (Teflon?) tubing. All compounds evaluated were stable in storage at 4 °C for 241 d (8 months). Concentrations of artificial sweeteners were consistently within 60% to 120% of original concentrations, except ACE and SAC that were substantially lower under acidified conditions at 25 °C after 241 d. Artificial sweetener concentrations remained nearly constant while in contact with all sampling materials except steel. SEM and TEM images showed oxidation of steel occurred; moreover, removal of all artificial sweetener compounds from aqueous solution had occurred after 289 d. These results suggest artificial sweetener analyses conducted within 14 d of sample collection produce optimal results; however, longer storage times may be acceptable under certain conditions. The results also suggest concentrations of artificial sweeteners in SGW are not affected by contact with typical well casing, sampling, and storage materials, with the exception of steel. The findings from this study will improve the use of artificial sweeteners as tracers in environmental studies.     

Regional debris-flow and debris-flood frequency–magnitude relationships

Construction of frequency–magnitude (F–M) relationships of debris floods and debris flows is challenging because of few direct observations, discontinuous event occurrence, loss of field evidence, the difficulty of accessing the sediment archive and the challenge of finding suitable statistical methods to analyse the dataset. Consultants often face budget limitations that prohibit application of the full gamut of absolute dating methods, stratigraphic analysis and analytical tools necessary to fully resolve the F–M legacy. In some cases, F–M curves are needed for watersheds without local information, or where obtaining this information is prohibitively expensive. For such watersheds, the F–M relationship may be estimated where several F–M curves have already been assembled in a specific region. Individual F–M curves are normalized by fan area or fan volume, then stratified by process type and geomorphic activity level. This paper describes the development of regional F–M curves for debris flows in southwestern British Columbia and debris flows and debris floods in the Bow River valley near Canmore, Alberta. We apply the regional relationships to other cases in Canada and the United States and demonstrate that the method can be globalized. The regional approach is compared to cases where detailed F–M relationships have been established by other means. Strong negative deviations from the regional debris-flow or debris-flood magnitude trends could signal inherent watershed stability, while strong positive deviations could signal extraordinary landslide processes, or suggest that the fan may be largely of paraglacial origin. We highlight some of these outlying cases and develop a method whereby the regional curves can be meaningfully adjusted, or reliance can be placed on lower or upper confidence bounds of the F–M curves. We caution against the indiscriminate use of the regionally based F–M curves, especially in watersheds where multiple geomorphic processes are active. © 2020 John Wiley & Sons, Ltd.     

Hillslope soil water flowpaths and the dynamics of roadside soil cation pools influenced by road deicers

Over the past 60 years, road deicers (i.e. road salt) have been applied to roadways in high latitudes to improve road conditions in winter weather. However, the dissolution of road deicers in highway runoff creates waters with high concentrations of sodium, which can mobilize soil metals via soil cation‐exchange reactions. While several studies have detailed the interactions of road salt‐rich solutions and surface and ground waters, less attention has been given to how local hydrologic flowpaths can impact the delivery of these solutions to near‐road soils. Between 2013 and 2014, soil water samples were collected from a roadside transect of lysimeter nests in Pittsburgh, Pennsylvania (USA). Soil water samples were analysed for metal concentrations and resulting data used to examine cation dynamics. While patterns in soil water calcium and magnesium concentrations follow patterns in soil water sodium concentrations, additional processes influence patterns in soil water potassium concentrations. Specifically, we observe the highest calcium and magnesium concentrations in the deepest lysimeters, suggesting divalent cations are mobilized to, and potentially accumulate in, deeper soil horizons. In contrast, soil water potassium concentrations do not follow this pattern. Additionally, in all examined elements (Ca, Mg, K, Na, and Cl), the timing of concentration peaks appears be influenced by a combination of both distance from the roadside and sampling depth. These relationships not only suggest that multiple soil water flowpaths interact with our study transect but also confirm that road salt plumes persist and migrate following the road salting season. Characterizing the interactions of sodium‐rich solutions and roadside soil cation pools clarifies our understanding of metal dynamics in the roadside environment. A deeper understanding of these processes is necessary to effectively restore and manage watersheds as high total dissolved solid solutions (e.g. road deicing melt, unconventional natural gas brines, and marginal irrigation water) continue to influence hydrological systems. Copyright © 2016 John Wiley & Sons, Ltd.     

Planning the use of fish for food security in the Pacific

Fish is a mainstay of food security for Pacific island countries and territories (PICTs). Recent household income and expenditure surveys, and socio-economic surveys, demonstrate that subsistence fishing still provides the great majority of dietary animal protein in the region. Forecasts of the fish required in 2030 to meet recommended per capita fish consumption, or to maintain current consumption, indicate that even well-managed coastal fisheries will only be able to meet the demand in 6 of 22 PICTs. Governments of many PICTs will need to increase local access to tuna, and develop small-pond aquaculture, to provide food security. Diversifying the supply of fish will also make rural households in the Pacific more resilient to natural disasters, social and political instability, and the uncertainty of climate change.     

The isotope hydrology of the Muskoka River Watershed,Ontario, Canada

Stable isotope tracers of δ¹⁸O and δ²H are increasingly being applied in the study of water cycling in regional-scale watersheds in which human activities, like river regulation, are important influences. In 2015, δ¹⁸O and δ²H were integrated into a water quality survey in the Muskoka River Watershed with the aim to provide new regional-scale characterization of isotope hydrology in the 5,100-km² watershed located on the Canadian Shield in central Ontario, Canada. The forest dominated region includes ~78,000 ha of lakes, 42 water control structures, and 11 generating stations, categorized as “run of river.” Within the watershed, stable isotope tracers have long been integrated into hydrologic process studies of both headwater catchments and lakes. Here, monthly surveys of δ¹⁸O and δ²H in river flow were conducted in the watershed between April 2015 and November 2016 (173 surface water samples from 10 river stations). Temporal patterns of stable isotopes in river water reflect seasonal influences of snowmelt and summer-time evaporative fractionation. Spatial patterns, including differences observed during extreme flood levels experienced in the spring of 2016, reflect variation in source contributions to river flow (e.g., snowmelt or groundwater versus evaporatively enriched lake storage), suggesting more local influences (e.g., glacial outwash deposits). Evidence of combined influences of source mixing and evaporative fractionation could, in future, support application of tracer-enabled hydrological modelling, estimation of mean transit times and, as such, contribute to studies of water quality and water resources in the region.     

Redacted in Nebraska: the noises of conspiracy around nuclear power problems

This paper investigates a ‘small story’, the problems around the Fort Calhoun nuclear power plant (Nebraska) in the wet summer of 2011. Relying on materials from digital media, it presents the official and an alternative version of events. Utilizing a constructionist approach, it identifies the search for moral certainty, as well as the importance of blame and conspiracy theories, from which emerges the ‘big story’. Highlighting the important role of on-line media and digital communication, we document not only the official story but also an opposing version based on a coherent worldview emphasising the problems of big government, liberal views and denial of American individual rights—all framed as a conspiracy covering-up a threatening, human-made technology failure. We suggest why this worldview occurs, stressing a widespread emphasis on American values and history, ‘failed journalism’, public uncertainty, the complexity of nuclear technology, and the specific uses of digital communication.     

Long-term biological effects of petroleum residues on fiddler crabs in salt marshes

In September 1969, the Florida barge spilled 700,000L of No. 2 fuel oil into the salt marsh sediments of Wild Harbor (Buzzards Bay, MA). Today the aboveground environment appears unaffected, but a substantial amount of moderately degraded petroleum still remains 8-20cm below the surface. The salt marsh fiddler crabs, Uca pugnax, burrow into the sediments at depths of 5-25cm, and are chronically exposed to the spilled oil. Behavioral studies conducted with U. pugnax from Wild Harbor and a control site, Great Sippewissett marsh, found that crabs exposed to the oil avoided burrowing into oiled layers, suffered delayed escape responses, lowered feeding rates, and achieved lower densities. The oil residues are therefore biologically active and affect U. pugnax populations. Our results add new knowledge about long-term consequences of spilled oil, a dimension that should be included when assessing oil-impacted areas and developing management plans designed to restore, rehabilitate, or replace impacted areas.